Enclosed are some pics of some messing around I started about a week ago and finished today. The top row is the hardware store silicone mold version, the bottom row the thermoformed HDPE mold version. The second pic is the thermoforming rig and materials.
The plug was designed in FreeCAD, 75mm x 75mm x 14mm with a round dimple on the smaller square face. That’s just about 3 x 3 x 5/8 inches.
The silicone mold plug was left in the plywood stock to help contain the silicone. I made the wall cavities for the silicone 3/8", next time I would only make it 1/4" or so. I added the top ring to make the mold bottom thickness closer to the sides. The wooden mold was sealed with epoxy. I sanded it a little, but was too curious to try it to finish it more. Then the mold was coated with mold release wax.
The silicone mix was about 3 fl oz of 100% silicone caulk, super-old and mined from a half-cured tube, 1.5 fl oz cornstarch, and some xylene in an attempt to thin it. I slopped the mix into the mold and went to the movies. I came back a few hours later and it had set. I waited a day and did the first wax pour. It still smells like xylene, perhaps that was not the best solvent to cut half-cured silicone…I read that the cornstarch is a carrier for moisture which the thicker sections of silicone need to cure but cannot draw from the surrounding air.
I had never done thermoforming before, at least not intentionally, so I searched online and read what I could find on Instructables, Youtube, and Hackaday. I made a little vacuum table, think miniature air hockey game table without the sides, about 10 x 15", with 1/16" holes on a 1/2" grid. The extra holes got covered with masking tape so only the holes under the plug and frame were in use. I made another plug out plain wood, no bottom or sides, no epoxy, and added holes to allow air to escape from the top and dimple of the plug.
I dug through the recycle bin and got a couple of HDPE jugs, the kind used for milk and windshield washer fluid in the US. I cut out the middles of the jug and made a plywood frame to staple the plastic to for its trip into the oven. The frame had drywall scew legs to allow heated air to both side of the plastic and so that it would not sag onto the cookie sheet and make a mess. Oven was set at 325 degrees F, I put the frame and the plug in and watched for the plastic to turn from cloudy to clear, only a couple of minutes. Then I turned on the vacuum attached to the vacuum table, put the plug in the middle, and pushed the heated HDPE over the plug and down to the table. Once the edge of the frame seals to the table it’s only a few seconds until the plastic is formed and turns cloudy again.
The first time I tried I did not heat the plastic enough and it did not draw around the plug, coaxing with a heat gun only caused the plastic to tear. Once heated evenly from cloudy to clear it formed easily. The level of detail is amazing-grain in the wood, sandpaper scratches, etc.-all in the plug and then reproduced in the mold. Once again, curiosity trumped tooling of the plug. I poured one of the HDPE molds with purple wax. Both bars are raspberry with coconut if anyone cares.
The results are crude in comparison to commercial products, but I enjoyed the process. If I were to take it to the next level it would be using nicer tooled plugs (no grain or scratches) and commercial materials: either ready-made thermoform sheets or a real 2-part, room-temp, mold-making silicone like Wooddave mentioned. I also tried a 2-part, heat-cure silicone from work, but the wooden mold acted as an insulator and kept the business surface of the mold from curing properly.