check this freely available info , 10 years old …
Following is some information on urethane foam and its dangers .
HAZARD DATA SHEET
URETHANE RESIN SYSTEMS
Monona Rossol, Health and Safety Officer for
United Scenic Artists, Local USA-829, IATSE
October 10, 1995
212/777-0062 or e-mail
75054.2542@compuserv. com
STRAIGHT TALK ABOUT URETHANE FOAM AND CASTING RESINS
“The resin part of a urethane product is not very hazardous. This is because it is not actually a “urethane resin.” Instead, it is any of several types of resins such as polyesters, polyethers, polyols, epoxies, and so on. These resins do not become “polyurethane” until they are reacted (cured, hardened, etc. ) with a diisocyanate. These diisocyanates are the problem.
Diisocyanate hardeners are capable of causing severe respiratory allergies and lung damage. Most notably, they cause a debilitating incurable occupational illness called “isocyanate asthma.” Sudden respiratory spasms and anaphylactic shock on exposure to diisocyanates also has resulted in death among workers using urethanes. There have been cases in which deaths occurred suddenly and without warning in people with no prior history of allergies.
To protect people from these effects, the American Conference of Governmental Industrial Hygienists set and extremely restrictive workplace air quality limit (Threshold Limit Value or TLV) for diisocyanates. To see just how incredibly restrictive (low) the TLV for diisocyanate is, the table on the following page compares it with TLVs for other substances.
TLVs OF VARIOUS CHEMICAL.S COMPARED TO DIISOCYANATES
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Substance Threshold Limit Values in parts per million
ethyl alcohol 1000.
rubbing alcohol 400.
mineral spirits 100.
toluene 50.
carbon tetrachloride 5.
phosgene (war gas) 0.1
methyl isocyanatel 0.02
diisocyanates** 0.005
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** This is the chemical that killed thousands of people in an accident in Bhopal, India
** The following are the diisocyanates which have been studied enough to set the 0.005 ppm TLV
-TDI (toluene diisocyanate), CAS # 584-84-9
-MDI (methylene bisphenyl isocyanate), CAS # 101-68-8
-hexamethylene diisocyanate, CAS # 82-06-0
-isophorone diisocyanate, CAS # 4098-71-9
-methylene bis(4-cyclohexylisocyanate),CAS # 5124-30-1
if you look above at the thresh hold limit in parts per million , youll see that while pentane isnt mentioned , it would fit in the same catorgary as mineral spirits , if you compare that figure with that of TDI , youll see TDI is a million times more toxic for the same given amount of exposure , then take into consideration that lightweight EPS is 98.7% air and 1.3% solid , then the 2.5 % of pentane used in EPS , was only present in 1.3 percent of the total …
so that leaves 0.065 % of lightweight EPS having pentane used in its production …
after the bead is expanded , the pentane evaporates out through the cell wall …
no details are available about the total volume of TDI by % used in urethane foam expansion , but unlike pentane , not all the TDI escapes the cell , so when you shape a board your actually still releasing cyanide gas in small amounts …
so while we are all guilty of making an impact on the enviroment , some practices are a million times worse …
literally …
surely you would have to question the foam you use when , an accident in india involving the spillage of TDI killed 5000 people just from the fumes released into the air …
i use epoxy and eps , because i can actually make better boards from it , there stronger ,lighter and go better …
im sure even if it was as toxic as urethane or worse , i would still be drawn to it because of performance , the fact its enviromentally friendlier than other options is just a bonus …
i think P/U has held surfers for so long because board builders have never even given EPS a fair assesment and gone past just having a go once or twice …
its almost amusing that the debate of fumes off a hotwire has been started , its almost as bad as blaming mine or gregs personality for not wanting to try alternatives …
the bottom line is ,what happened to clark , will also plague all blank manufacturers in developed nations in the future …
if a chemical can kill 5000 people than its surely going to have the attention of the EPA …
clarks closure was a wake up call , but it looks like a few crew slept right through the alarm …
regards
BERT